Development of all-solid-state thin-film device for on-demand control both of infared transmittance and conductivity at room temperature -Progress toward the realization of smart window-
Research Press Release | June 29, 2015
|Key Points||The Research Institute for Electronic Science successfully developed an all-solid-state thin-film device with the ability to control both infrared-light transmittance and electric current at the same time (Figure 1).
Electrochromic materials are essential to develop electronic devices which control both of light transmittance and electrical conductivity at the same time. Tungsten trioxide (WO3), a representative electrochromic material, has been applied for color-switching windows in airplanes;however, the electrochromism of WO3 reduces the transmittance of visible-light along with that of infrared (IR), thus makes it impossible for WO3 to control only the IR transmittance while keeping the visible-light transparency.
|Overview||This research team focused on vanadium dioxide (VO2), which is a classically well-known thermochromic material. VO2 shows an abrupt change of the optical transmission only in the infrared region along with the insulator-to-metal transition when heated to the transition temperature of 68○C. Non-doped VO2 is an insulator and transparent for visible-light and IR, but the protonated VO2 (HxVO2) is a metal and opaque to IR while maintaining visible-light transparency. Therefore, protonation and deprotonation of VO2 can develop light-control glasses with functionality of switching only IR, but protonation of VO2 needs imperative high-temperature heat treatment in hydrogen gas and electrochemical reaction through electrolysis of an aqueous solution, which have been unsuited for practical purposes.
Here we have demonstrated solid-state protonation and deprotonation of VO2 thin film at RT by using a thin film transistor (TFT) structure with a gate insulator of water-infiltrated nano-porous glass (CAN) [Ref. 1], which works like a sponge and automatically adsorbs water vapor in air (Figure 2). A positive gate bias application induces water electrolysis in the solid CAN gate insulator, and produced electro-active H+ ions are used to protonate the VO2 channel layer. As a result, sheet resistance and absolute value of thermopower significantly decreased, i.e. the electronic state changed from insulator to metal by protonation of VO2 at RT. The protonation was clearly accompanied by the structural change from monoclinic VO2 to tetragonal HxVO2 phase. On the other hand, negative gate bias application induced deprotonation of VO2, where the metallic state recovered to insulating one. These results prove that we have succeeded to demonstrate the fabrication of all-solid-state thin-film device, which doesn’t require the high-temperature and liquid electrolyte.
The reversible protonation and deprotonation of VO2 under an applied voltage at RT offer a new route to all-solid-state smart windows; e.g. the electro-optical device that can realize the on-demand shielding of transmittance of IR light, which disturbs the control of ambient temperature, and electrical switching of air conditioner.
This research was conducted in collaboration with Prof. Takayoshi Katase, Prof. Hiromichi Ohta (Laboratory of Functional Thin Film Materials, RIES), and Prof. Tetsuya Tohei, Prof. Yuichi Ikuhara (Institute of Engineering Innovation, The University of Tokyo). A part of this work was supported by JSPS KAKENHI for Scientific Research A (25246023), Young Scientists A (15H05543), and Scientific Research on Innovative Areas (25106007).
Authors： Takayoshi Katase*, Kenji Endo, Tetsuya Tohei, Yuichi Ikuhara, and Hiromichi Ohta*
Title： Room-temperature-protonation-driven on-demand metal-insulator conversion of a transition metal oxide
[Ref. 1] H. Ohta et al., “Field-induced water electrolysis switches an oxide semiconductor from an insulator to a metal”, Nature Communications 1, 118 (2010)
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Room-temperature-protonation-driven on-demand metal-insulator conversion of a transition metal oxide, Advanced Electronic Materials (electronic version) (2015.6.1)